(Re)Counting the poor in Peru: a multidimensional approach

After an impressive 12 point reduction in Peruvian monetary poverty, questions have been raised about the extent in which these figures mask deprivation in several other aspects critical for human development. We propose using the Alkire-Foster multidimensional headcount to address this issue, and devise a simple comparison framework to measure the tension between the incidence of monetary poverty and the overall level of deprivation based on the multidimensional measure. We select six dimensions and their respective indicators for the Peruvian case, and apply this framework using data for 2004 and 2008. Results indicate that we now face a larger risk of classifying as non-poor individuals who still endure significant deprivation if we rely on the conventional monetary dimension. In addition, inter and intraregional comparisons show that deprivations endured by the multidimensional poor are similar across regions and concentrated on the health and dwelling conditions dimensions, in particular, on the lack of adequate water and sanitation services. This last result reveals an opportunity to focalize public investment efforts.Multidimensional poverty; monetary poverty; Peru.

Flow injection determination of total catechins and procyanidins in white and red wines

An easily automatable flow-injection (FI) method for the determination of total catechins is reported. The method is based on the reaction of vanillin in acid medium to yield a coloured product with maximum absorption at 500 nm. After optimisation by the univariate and multivariate approaches as required, the linear range was established (between 10 and 90 mgL-1 and 10 and 250 mgL-1 for white and red wines, respectively). Then, the assessment of the proposed versus the reference method was studied in terms of repeatability (2.57 mgL-1), reproducibility (3.56 mgL-1) (no significant differences were found), detection and quantification limits (not far from those of the reference method and always sufficient for the determination of catechins in any type of wine), traceability (excellent correlation under all conditions) and sample throughput (23 samples h-1 for the proposed method versus 3 samples h-1 for the reference method)

LISA pathfinder micronewton cold gas thrusters: in-flight characterization

The LISA Pathfinder (LPF) mission has demonstrated the ability to limit and measure the fluctuations in acceleration between two free falling test masses down to sub-femto-g levels. One of the key elements to achieve such a level of residual acceleration is the drag free control. In this scheme the spacecraft is used as a shield against any external disturbances by adjusting its relative position to a reference test mass. The actuators used to move the spacecraft are cold gas micropropulsion thrusters. In this paper, we report in-flight characterization of these thrusters in term of noise and artefacts during science operations using all the metrology capabilities of LISA Pathfinder. Using the LISA Pathfinder test masses as an inertial reference frame, an average thruster noise of ~0.17¿¿µN/Hz is observed and decomposed into a common (coherent) and an uncorrelated component. The very low noise and stability of the onboard metrology system associated with the quietness of the space environment allowed the measurement of the thruster noise down to ~20¿¿µHz, more than an order of magnitude below any ground measurement. Spectral lines were observed around ~1.5¿¿mHz and its harmonics and around 55 and 70 mHz. They are associated with the cold gas system itself and possibly to a clock synchronization issue. The thruster noise-floor exhibits an excess of ~70% compared to characterization that have been made on ground on a single unit and without the feeding system. However this small excess has no impact on the LPF mission performance and is compatible with the noise budget for the upcoming LISA gravitational wave observatory. Over the whole mission, nominal, and extension, the thrusters showed remarkable stability for both the science operations and the different maneuvers necessary to maintain LPF on its orbit around L1. It is therefore concluded that a similar cold gas system would be a viable propulsion system for the future LISA mission.Peer ReviewedPostprint (author's final draft

Novel methods to measure the gravitational constant in space

We present two novel methods, tested by LISA Pathfinder, to measure the gravitational constant G for the first time in space. Experiment 1 uses electrostatic suspension forces to measure a change in acceleration of a test mass due to a displaced source mass. Experiment 2 measures a change in relative acceleration between two test masses due to a slowly varying fuel tank mass. Experiment 1 gave a value of G=6.71±0.42(×10-11)¿¿m3¿s-2¿kg-1 and experiment 2 gave 6.15±0.35(×10-11)¿¿m3¿s-2¿kg-1, both consistent with each other to 1s and with the CODATA 2014 recommended value of 6.67408±0.00031(×10-11)¿¿m3¿s-2¿kg-1 to 2s. We outline several ideas to improve the results for a future experiment, and we suggest that a measurement in space would isolate many terrestrial issues that could be responsible for the inconsistencies between recent measurements.Peer ReviewedPostprint (published version

Temperature stability in the sub-milliHertz band with LISA Pathfinder

This article has been accepted for publication in "Monthly notices of the royal astronomical society" published by Oxford University Press.LISA Pathfinder (LPF) was a technology pioneering mission designed to test key technologies required for gravitational wave detection in space. In the low frequency regime (milliHertz and below), where space-based gravitational wave observatories will operate, temperature fluctuations play a crucial role since they can couple into the interferometric measurement and the test masses’ free-fall accuracy in many ways. A dedicated temperature measurement subsystem, with noise levels in 10¿µK¿Hz-1/2 down to 1¿mHz was part of the diagnostics unit onboard LPF. In this paper we report on the temperature measurements throughout mission operations, characterize the thermal environment, estimate transfer functions between different locations, and report temperature stability (and its time evolution) at frequencies as low as 10¿µHz, where typically values around 1¿K¿Hz-1/2 were measured.Peer ReviewedPreprin

Flow injection determination of readily assimilable nitrogen compounds during vinification

A flow injection method for the determination of readily assimilable nitrogen (r.a.n.), i.e. ammonium and aminated nitrogen, is reported. The difference in pH of the sample in the presence and absence of formaldehyde, which blocks the amino function, provides the value of r.a.n. by monitoring the changes in absorbance of bromothymol blue at 616 nm. The detection and quantification limits are 10 and 11.6 mg l-1, respectively; the reproducibility and repeatability are 3.94 mg l-1 and 1.35 mg l-1, respectively; and the sample throughput is 20 samples h-1. The method has been applied to the analysis of 120 samples of must and wine subjected to biological aging. The proposed method also provides good correlation with the reference method used in routine analysis, and it is faster and gives sufficient precision for wineries requirements

Desdolarizando la economía peruana: Un enfoque de portafolio

La visión de consenso es que la dolarización financiera complica el diseño de la política económica, al abrir la puerta a un mayor grado de vulnerabilidad financiera. A pesar de esto, en la última década no hubo un esfuerzo explícito por reducir el nivel de dolarización junto con el programa de estabilización. Además de presentar un conjunto de indicadores para cuantificar cada tipo de dolarización, así como sus resultados para la economía peruana, en este estudio se evalúan distintas medidas para combatir el fenómeno de dolarización financiera. Para esto, y atendiendo a los resultados obtenidos, se privilegia el enfoque de portafolio y se analizan los efectos de modificar el grado de cobertura del seguro de depósitos y la varianza relativa de la inflación y la devaluación real. Los resultados permiten adelantar que una reducción en la cobertura de dicho seguro para depósitos en dólares no se traduciría en un menor ratio de dolarización, ya que propiciaría una transferencia de recursos hacia el exterior. La balanza se inclina hacia aquellas medidas orientadas a reducir la volatilidad de la inflación respecto a la de la devaluación real.

Use of superheated liquids for the extraction of non-volatile compounds from wood: HPLC studies

A study of the extraction of oak wood compounds using superheated water-ethanol mixtures ranging from 10 to 60% ethanol is reported. Identification and characterization of the extracted compounds have been made by high performance liquid chromatography. The extraction has been performed using the static mode by single or repetitive cycles. The variables affecting the extraction process have been studied and their optimum values established (extraction time: 50 min; pressure: 40 atm; extraction temperature: 180º C). The study allows to compare the non-volatile polyphenol fractions obtained in this way with those present in commercial samples with fully agreement between them. In addition, the method allows manipulation of the extract composition by changing the working pressure, temperature and water-ethanol ratio

Method for monitoring urea and ammonia in wine and must by flow injection-pervaporation

An easy to automate flow-injection-pervaporation method for monitoring urea and ammonia in must and wine was developed. The method is based on separation of the ammonia from the sample matrix by pervaporation followed by its reaction with salicylate, hypochlorite and nitroprusside to form a diazonium salt with maximum absorption at 647 nm. Conversion of urea into ammonia catalysed by urease was mandatory before pervaporation. After optimisation by either the univariate or multivariate approaches as required, the linear range was established (between 0 and 25 mg l-1) for both analytes. Then, the assessment of the proposed method versus a reference one for urea and ammonia was studied in terms of repeatability (0.52 mg l-1 and 0.43 mg l-1, respectively), reproducibility (1.34 mg l-1 and 1.21 mg l-1, respectively), detection and quantification limits (LOD=0.9 and 0.6 mg l-1, LQ=1.02 and 0.67 mg l-1, respectively) and traceability. The sample throughput was 16 samples h-1. The method can be applied to the monitoring of the target analytes in must and young wine in order to control their contents, preventing formation of ethyl carbamate